What's your impression on the '94 now vs '85 then? Is that '94-95 are better vintages and their young profile today is reflective of a better vintage? Does retrospection cloud an impartial review?
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Moderators: Glenn E., Roy Hersh, Andy Velebil
VA is something that never goes away and it never "blows off." It only will get worse over time.Tom Archer wrote:'94 is the vintage that keeps running away from me..
At the end of 2008 I concluded that VPs under 18 years old were neither very enjoyable nor informative drinking choices, so I stopped opening them at home. In 2012, having reached the requisite age I opened just one '94 (a Cockburn) before putting the minimum age back to 21, and put it back again to 24 years before 2015 had dawned.
Well 2018 has now dawned, and the 94's have reached their majority (again..) and finally I will (sometime this year..) revisit the '94s for home consumption..
So I can't really comment on '85 vs '94 then and now; but can observe that a decade ago, there was no contest between the mainstream '75 and '85 VPs - the 85's were mostly very much better (Croft and Cockburn excepted). Today however the 75s have improved remarkably whilst many 85s are looking a bit ragged. I'm quietly confident though that those '85s that are not plagued by VA will find a serene maturity in another decade, just as the '75s have done.
And of those that are VA afflicted? I'm intrigued to know how this fault will evolve over time. One doesn't encounter VA in very old bottles, but you do occasionally get a varnishy one - I wonder if that is the natural destiny of VA - or something completely different..?
Not sure I agree with that. There's quite a cocktail of chemical reactions slowly taking place in wine and the causal compounds that give the VA 'experience' are not immune from involvement. Some of the worst VA symptoms are probably down to the presence of the obnoxious smelling butyric acid; however this might over time react slowly with the ethanol in the wine to form ethyl butyrate - which has a very pleasant aroma..VA is something that never goes away and it never "blows off." It only will get worse over time.
This will explain VA in wine, how it gets there and what it does. Basically, once it's there it never goes away. Though you can control it prior to bottling. Once in bottle there is nothing you can do about it.Tom Archer wrote:Not sure I agree with that. There's quite a cocktail of chemical reactions slowly taking place in wine and the causal compounds that give the VA 'experience' are not immune from involvement. Some of the worst VA symptoms are probably down to the presence of the obnoxious smelling butyric acid; however this might over time react slowly with the ethanol in the wine to form ethyl butyrate - which has a very pleasant aroma..VA is something that never goes away and it never "blows off." It only will get worse over time.
So whilst I wouldn't put much money on the faulty '85s healing themselves, one should never say never..!
If that was true, very old bottles would sometimes display the same fault 'signature' as a young one - but as that's not my experience, I feel there must be some evolution..Basically, once it's there it never goes away.
It only gets worse...that's the only evolution. VA will "bloom" if the wine is exposed to warm temps. Why sometimes some bottles show more than others of the same wine/vintage. Speak to anyone experienced in the wine industry and they will tell you the same. If you don't control it during fermentation, aging in barrel and prior to bottling, it's a ticking time bomb that you can't reverse.Tom Archer wrote:If that was true, very old bottles would sometimes display the same fault 'signature' as a young one - but as that's not my experience, I feel there must be some evolution..Basically, once it's there it never goes away.
That was an interesting and reasonable read, but I think it overemphasized acetobacter and acetic acid as the basis of VA. It mentioned that "there are a few rogue yeasts that can do the same thing," but it still seemed to put that in the acetic acid and ethyl acetate field. I find this explanation more complete:Andy Velebil wrote:This will explain VA in wine, how it gets there and what it does. Basically, once it's there it never goes away. Though you can control it prior to bottling. Once in bottle there is nothing you can do about it.
https://winemakermag.com/676-the-perils ... le-acidity
Acetobacter needs air, but there are other producers of VA that will gladly work in an anaerobic environment. Brett will work with or without oxygen, and butyric acid is produced from anaerobic fermentation ...But the bugs also need one other thing to trigger the reaction — air.
“What you have to control is the oxygen,” Bisson said.
You didn't counter it.It was a good overview to counter Tom's point.
I'm with Tom on this as well. The things that make VA are there in the bottle. The chemicals are produced. I don't think that some of those (acetic acid) are subject to further chemical reactions, but some of them could be, and the article doesn't say one way or the other. And the perception of these may change as other reactions take place in the bottle. "Hey, this tastes so much like wet cardboard now that I can barely notice the vomit flavor."Tom Archer wrote:You didn't counter it.It was a good overview to counter Tom's point.
It's hard to compare something that is consumed in small quantities due to it's old age and rarity and use that as the basis for your argument. Especially when it comes to VA, as this points out, sensory threshold for most is quite high. Like TCA, some are more sensitive to it than others. That doesn't change the fact that it's still there. And everything I've ever read and been told by winemakers is that excess VA perception only gets worse as time goes on.Tom Archer wrote:You didn't counter it.It was a good overview to counter Tom's point.
My key point is that very old faulty bottles do not show the same range of bad characteristics as young ones, which strongly suggests that the maturation process (a complex of slow chemical reactions) also includes reactions of the fault causing chemicals, thereby changing their perceived effect on the wine.
You stated baldly that VA is VA and is there for evermore. The evidence does not support that.
Your argument is that as a bottle gets old it somehow gets rid of or covers up that VA fault. And that it somehow magically goes away or lessens. However, all studies and decades of research clearly say that VA never goes away. The only way to remove excess amounts of it in wine is by reverse osmosis.The sensory threshold for acetic acid is between 0.7 – 1.2 g/L for most individuals, and many are surprised at how challenging it can be to smell acetic acid before the levels rise near legal limits. As defined by the Standards of Identity in the Code of Federal Regulations (27 CFR), “the maximum volatile acidity, calculated as acetic acid and exclusive of sulfur dioxide is 0.14 g/100 mL for red wine (1.4 g/L) and 0.12 g/100 mL (1.2 g/L) for white wines.” There are some allowances for higher maximum VA concentrations for wines produced from unameliorated juice up to 28°Brix.
Your comments about why old wines you drink don't show the flaw I'd give these simple answers. 1) You have a very high threshold for perceiving it. 2) Seriously flawed wines are generally not kept for long. People either drink or get rid of them young. So the odds of large quantities of seriously VA flawed wines surviving for 40+ years is quite small.Higher VA wines (>0.7 g/L) are a greater issue, and it may be challenging to blend them away or they may have to be blended away in small quantities over time. The only practical option for wines with a very high VA is the use of reverse osmosis (RO), which can often be contracted out to various wine technology companies. RO can be costly and depending on the company, it may not be a practical solution to minimize ethyl acetate concentrations.
Probably rarer in the US, but I actively seek out and consume ancient bottles of both port and unfortified wine - I get though roughly fifty bottles a year that are over fifty years old, so have a pretty good take on this.It's hard to compare something that is consumed in small quantities due to it's old age and rarity and use that as the basis for your argument.
And everything I've ever read and been told by winemakers is that excess VA perception only gets worse as time goes on.
Quite often they get passed over and abandoned in the cellar until the owner dies..Seriously flawed wines are generally not kept for long.
I think there are chemical reactions that change the nature of the VA to some degree, as there is no consistency with ageYour argument is that as a bottle gets old it somehow gets rid of or covers up that VA fault.
I've offered scientific links that clearly point out that VA doesn't change and it doesn't go away once in bottle. Please link some kind of scientific study or something other than "I've tasted old wine and they don't have issues" therefore old wines somehow magically change VA. So far you've offered up hocus pocus theories based on not one shred of known science.Tom Archer wrote:Probably rarer in the US, but I actively seek out and consume ancient bottles of both port and unfortified wine - I get though roughly fifty bottles a year that are over fifty years old, so have a pretty good take on this.It's hard to compare something that is consumed in small quantities due to it's old age and rarity and use that as the basis for your argument.
And everything I've ever read and been told by winemakers is that excess VA perception only gets worse as time goes on.
Remember that wine makers think in terms of weeks and months and many of them very rarely get to drink seriously old wines. At a dinner party in Gaia a couple of years ago I was seated next to a senior wine maker who told me he'd never tasted a '55 before..
Quite often they get passed over and abandoned in the cellar until the owner dies..Seriously flawed wines are generally not kept for long.
I think there are chemical reactions that change the nature of the VA to some degree, as there is no consistency with ageYour argument is that as a bottle gets old it somehow gets rid of or covers up that VA fault.
From my previous linked article from UCDavis:Eric Ifune wrote:I think we are talking about different things here. Classic VA is a stable compound produced by aerophillic bacteria as Andy alludes to. There are other compounds that other organisms can produce in a variety of environments which can be similar in effect. One would need chromatography to figure them all out.
Volatile acidity refers to the steam distillable acids present in wine, primarily acetic acid but also lactic, formic, butyric, and propionic acids. Commonly, these acids are measured by Cash Still, though now they can be measured by gas chromatography, HPLC or enzymatic methods. The average level of acetic acid in a new dry table wine is less than 400 mg/L, though levels may range from undetectable up to 3g/L.
Over weeks and months these chemicals may well appear stable, but over decades? As far as I am aware, the scientific research simply hasn't been done.I've offered scientific links that clearly point out that VA doesn't change and it doesn't go away once in bottle.
They have lots of issues, but the point I'm trying to get through to you is that they have different issues. The lack of continuity has to have a reason.something other than "I've tasted old wine and they don't have issues"
Do you have a link to that? It would be interesting reading to read a 50 year study of the same wine's chemical evolution, although if they were measuring VA by the Cash Still or Gas Chromatography methods the results would be meaningless, as the processes themselves are only suitable for compounds that are stable enough to be gasified and would probably degrade the complex compounds formed from the VA back to VA itself.Long term research on this says it doesn't over time.